However, I've found what caused it!
- If you right click the drive that you need to provide permission to and select properties...
- Select the Security tab
- Click Advanced
- Click Change Permissions
- Select the group that needs to be changed (in this example, the administrators group)
- Click Edit
- Note the tick box at the bottom... 'Apply these permissions to objects and/or containers within this container only'. Untick this option
- Click OK to save out of the various screens. You may have to tick the box to 'Replace all child object permissions with inheritable permissions from this object' so that the new permissions flow down to the sub-folders.